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ASTM D4839-03(2017)

Standard Test Method for Total Carbon and Organic Carbon in Water by Ultraviolet, or Persulfate Oxidation, or Both, and Infrared Detection

1.1 This test method covers the determination of total carbon (TC), inorganic carbon (IC), and total organic carbon (TOC) in water, wastewater, and seawater in the range from 0.1 mg/L to 4000 mg/L of carbon.

1.2 This test method was used successfully with reagent water spiked with sodium carbonate, acetic acid, and pyridine. It is the user's responsibility to ensure the validity of this test method for waters of untested matrices.

1.3 This test method is applicable only to carbonaceous matter in the sample that can be introduced into the reaction zone. The syringe needle or injector opening size generally limit the maximum size of particles that can be so introduced.

1.4 In addition to laboratory analyses, this test method may be applied to stream monitoring.

1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.


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