Historical

ASTM D7833-12

Standard Test Method for Determination of Hydrocarbons and Non-Hydrocarbon Gases in Gaseous Mixtures by Gas Chromatography

1.1 This test method is intended to quantitatively determine the non-condensed hydrocarbon gases with carbon numbers from C1 to C5+ and non-hydrocarbon gases, such as H2, CO2, O2, N2, and CO, in gaseous samples. This test method is a companion standard test method to Test Method D1945 and Practice D1946 differing in that it incorporates use of capillary columns instead of packed columns and allows other technological differences.

1.2 Hydrogen sulfide can be detected but may not be accurately determined by this procedure due to loss in sample containers or sample lines and possible reactions unless special precautions are taken.

1.3 Non-hydrocarbon gases have a lower detection limit in the concentration range of 0.03 to 100 mole percent using a thermal conductivity detector (TCD) and C1 to C6 hydrocarbons have a lower detection limit in the range of 0.005 to 100 mole percent using a flame ionization detector (FID); using a TCD may increase the lower detection limit to approximately 0.03 mole percent.

1.3.1 Hydrocarbon detection limits can be reduced with the use of pre-concentration techniques and/or cryogenic trapping.

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