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Airborne Particles

Airborne particle testing standards are published by ISO, ASTM, BS, PD, and CSA. ISO standards cover sampling of welding operator breathing zones, test bench method for measurement of pollutant concentration parameter, determination of size distribution using differential electrical mobility analyzing systems, determination of inorganic acids by ion chromatography, controlling uncertainty in weighing collected aerosols, inhalation exposure of ultrafine, nanoparticle and non-structured aerosols, determination of mercury by cold vapor atomic absorption spectrometry or atomic fluorescence spectrometry, determination of lead by flame or electrothermal atomic absorption spectrometry, determination of settled fibrous dust by scanning electron microscopy, and environmental tobacco smoke. ASTM standards cover measurement of respirable silica by infrared spectrometry, determination of metals by inductively coupled plasma atomic emission spectrometry, determination of lead by flame or graphite furnace atomic absorption spectrometry, determination of hexavalent chromium by ion chromatography, monitoring diesel particulate exhaust, personal samplers of health-related aerosol fractions, determination of airborne single-crystal ceramic whiskers by transmission electron, scanning electron, and phase contrast microscopy, and estimating contribution of environmental tobacco smoke based on solanesol and UVPM and FPM. BS standards cover assessment of sampler performance based on determination of sampling efficiency and comparison of concentrations, measuring a chemical agent present as a mixture of airborne particles and vapor, requirements for evaluation of measuring procedures, determination of concentration of chemical agents, size fraction definitions for measurement of airborne particles, protective clothing, safety of machinery, determination of metals by inductively coupled plasma atomic emission spectrometry sampling, determination of hexavalent chromium by ion chromatography and spectrophotometric measurement using diphenyl carbazide, dand determination of particle size distribution using light scattering airborne particle counters.The PD standard covers guidance for sampling of inhalable, thoracic, and respirable aerosol fractions. Finally, the CSA standard covers guidelines for calculating the radiological consequences to the public of a release of airborne radioactive material.


ISO 10882-1:2011

Health and safety in welding and allied processes - Sampling of airborne particles and gases in the operators breathing zone - Part 1: Sampling of airborne particles

ISO 10882-1:2011 specifies a procedure for sampling airborne particles in the breathing zone of a person who performs welding and allied processes (the operator). It also provides details of relevant standards that specify required characteristics, performance requirements and test methods for workplace air measurement, and augments guidance provided in EN 689 on assessment strategy and measurement strategy. ISO 10882-1:2011 also specifies a procedure for making gravimetric measurements of personal exposure to airborne particles generated by welding and allied processes (welding fume) and other airborne particles generated by welding-related operations. Additionally, it provides references to suitable methods of chemical analysis, specified in other standards, to determine personal exposure to specific chemical agents present in welding fume and other airborne particles generated by welding-related operations. The general background level of airborne particles in the workplace atmosphere influences personal exposure and therefore the role of fixed-point sampling is also considered.


ISO 29042-7:2010

Safety of machinery - Evaluation of the emission of airborne hazardous substances - Part 7: Test bench method for the measurement of the pollutant concentration parameter

ISO 29042-7:2010 specifies a test bench method for the measurement of the pollutant concentration parameter of a given airborne hazardous substance from a machine, using a test bench under specified operating conditions. The method is applicable only to the determination of emitted gases, vapours and respirable particles.


ISO 28439:2011

Workplace atmospheres - Characterization of ultrafine aerosols/nanoaerosols - Determination of the size distribution and number concentration using differential electrical mobility analysing systems

ISO 28439:2011 provides guidelines for the determination of the number concentration and size distribution of ultrafine aerosols and nanoaerosols by use of mobility particle sizers (also called differential mobility analysers). Only the particle fraction of the aerosol is considered. For ultrafine aerosols and nanoaerosols, exposure metrics such as the number and surface area concentration are important. ISO 28439:2011 also gives guidelines for the determination of workplace exposure to ultrafine aerosols and nanoaerosols. Specifically, the differential mobility analysing system (DMAS), now available from several vendors, is discussed. Principles of operation, problems of sampling in the workplace environment, calibration, equipment maintenance, measurement uncertainty, and reporting of measurement results are covered. Potential problems and limitations are described, which need to be addressed when limit values are fixed and compliance measurements carried out.


ISO 21438-1:2007

Workplace atmospheres - Determination of inorganic acids by ion chromatography - Part 1: Non-volatile acids (sulfuric acid and phosphoric acid)

ISO 21438-1:2007 specifies a method for the determination of the time-weighted average mass concentration of sulfuric acid and phosphoric acid in workplace air by ion chromatography. The method is applicable to the personal sampling of the inhalable fraction of airborne particles, as defined in ISO 7708 and to static (area) sampling. The analytical method is applicable to the determination of masses of 0,005 mg to 2,000 mg of sulfuric acid and phosphoric acid per sample, without dilution. The concentration range of sulfuric acid and phosphoric acid in air for which the measuring procedure is applicable is determined by the sampling method selected by the user. For an air sample of volume 1 m 3 , the working range is approximately 0,005 mg/m 3 to 2,000 mg/m 3 . The method is not applicable to the determination of sulfur trioxide. The procedure does not allow differentiation between the acids and their corresponding salts if both are present in the air. The procedure does not allow differentiation between phosphoric acid and diphosphorus pentoxide (phosphoric anhydride) if both are present in the workplace.


ISO 21438-2:2009

Workplace atmospheres - Determination of inorganic acids by ion chromatography - Part 2: Volatile acids, except hydrofluoric acid (hydrochloric acid, hydrobromic acid and nitric acid)

ISO 21438-2:2009 specifies a method for the determination of the time-weighted average mass concentration of hydrogen chloride (HCl) gas and hydrochloric acid mist, hydrogen bromide (HBr) vapour and hydrobromic acid mist and nitric acid (HNO 3 ) vapour and mist in workplace air by collection on an alkali-impregnated quartz fibre filter and analysis by ion chromatography. For mist sampling, the method is applicable to the personal sampling of the inhalable fraction of airborne particles and to static (area) sampling. The analytical method is applicable to the determination of masses of 0,01 mg to 2,5 mg of HCl, HBr and HNO 3 per sample. The range of concentrations of HCl, HBr and HNO 3 in air for which the measuring procedure is applicable is determined by the sampling method selected by the user. For a 240-litre air sample, the working range is approximately 0,04 mg/m 3 to 10 mg/m 3 for HCl, HBr and HNO 3 . The procedure is intended to differentiate between the acids and their corresponding salts. If both are present in the air, particulate salts are trapped on a pre-filter. Co-sampled particulate matter trapped on the pre-filter and/or deposited on the walls of the sampler may be analysed, if desired. Acids can react with co-sampled particulate matter on the pre-filter, causing interference with the measurement of the acid concentration.


ISO 21438-3:2010

Workplace atmospheres - Determination of inorganic acids by ion chromatography - Part 3: Hydrofluoric acid and particulate fluorides

ISO 21438-3:2010 specifies a method for the determination of the time-weighted average mass concentration of soluble particulate fluorides and hydrofluoric acid (HF) in workplace air by collection of the particulate fluorides on a pre-filter and HF on an alkali-impregnated filter and analysis by ion chromatography. The method is only applicable to determination of particulate fluorides that are soluble using the sample preparation procedure specified. For aerosol sampling, the method is applicable to the personal sampling of the inhalable fraction of airborne particles, as defined in ISO 7708, and to static (area) sampling. The method is applicable to the determination of masses of 0,005 mg to at least 1,25 mg of particulate fluorides per sample and 0,012 5 mg to at least 1,2 mg of HF per sample. The concentration range of particulate fluorides and HF in air for which the measuring procedure is applicable is determined by the sampling method selected by the user. For a 120 l air sample, the working range is approximately 0,04 mg m - 3 to at least 10 mg m - 3 for particulate fluorides and approximately 0,13 mg m - 3 to at least 10 mg m - 3 for HF. HF can react with co-sampled particulate matter on the pre-filter, causing an interference on the measured concentration.


ISO 15767:2009

Workplace atmospheres - Controlling and characterizing uncertainty in weighing collected aerosols

ISO 15767:2009 provides recommendations for controlling the analytical uncertainty associated with aerosol collection medium instability, where collection medium or collection substrate includes any article used to collect particles (e.g. filter or foam material) as well as those supporting elements which must be analysed by weighing. ISO 15767:2009 is applicable to results compiled both from the literature and, if necessary and feasible, through laboratory experiment. Expected uncertainty associated with given aerosol capture methods is quantified where possible. Recommendations as to materials to be used are given. Means of minimizing uncertainty arising from instability are provided. Recommendations for the weighing procedure are given. A procedure for estimating weighing uncertainty is described. Finally, recommendations are given for the reporting of measured mass, including an uncertainty component and limits of detection and quantification.


ISO/TR 27628:2007

Workplace atmospheres - Ultrafine, nanoparticle and nano-structured aerosols - Inhalation exposure characterization and assessment

ISO/TR 27628:2007 contains guidelines on characterizing occupational nanoaerosol exposures and represents the current state-of-the-art, with an emphasis on nanometre-diameter particles. Background information is provided on the mechanisms of nanoaerosol formation and transportation within an occupational setting and on industrial processes associated with nanoaerosol exposure. Exposure metrics appropriate to nanoaerosols are discussed, and specific methods of characterizing exposures with reference to these metrics are covered. Specific information is provided on methods for bulk aerosol characterization and single particle analysis.


ISO 17733:2015

Workplace air - Determination of mercury and inorganic mercury compounds - Method by cold-vapour atomic absorption spectrometry or atomic fluorescence spectrometry

ISO 17733:2015 specifies a procedure for determination of the time-weighted average mass concentration of mercury vapour and inorganic mercury compounds in workplace air. Mercury vapour is collected on a solid sorbent using either a diffusive badge or a pumped sorbent tube. Particulate inorganic mercury compounds, if present, are collected on a quartz fibre filter. Samples are analysed using either cold vapour atomic absorption spectrometry (CVAAS) or cold vapour atomic fluorescence spectrometry (CVAFS) after acid dissolution of the mercury collected. This International Standard is applicable to the assessment of personal exposure to mercury vapour and/or particulate inorganic mercury compounds in air for comparison with long-term or short-term exposure limits for mercury and inorganic mercury compounds and for static (area) sampling. The lower limit of the working range of the procedure is the quantification limit. This is determined by the sampling and analysis methods selected by the user, but it is typically in the range 0,01 µg to 0,04 µg of mercury (see 13.1). The upper limit of the working range of the procedure is determined by the capacity of the diffusive badge, sorbent tube or filter used for sample collection, but it is at least 30 µg of mercury (see 13.2). The concentration range of mercury in air for which this International Standard is applicable is determined in part by the sampling method selected by the user, but it is also dependent on the air sample volume. The diffusive badge method is not applicable to measurements of mercury vapour when chlorine is present in the atmosphere, e.g. in chloralkali works, but chlorine does not interfere with the pumped sorbent tube method (see 13.12.1). Gaseous organomercury compounds could cause a positive interference in the measurement of mercury vapour (see 13.12.2). Similarly, particulate organomercury compounds and gaseous organomercury compounds adsorbed onto airborne particles could cause a positive interference in the measurement of particulate inorganic mercury compounds (see 13.12.3).


ISO 8518:2001

Workplace air - Determination of particulate lead and lead compounds - Flame or electrothermal atomic absorption spectrometric method

This International Standard specifies flame and electrothermal atomic absorption spectrometric methods for the determination of the time-weighted average mass concentration of particulate lead and lead compounds in workplace air. The method is applicable to personal sampling of the inhalable fraction of airborne particles, as defined in ISO 7708, and to static (area) sampling. The sample dissolution procedure specifies hot plate or microwave digestion, or ultrasonic extraction (11.2). The use of an alternative, more vigorous dissolution procedure is necessary when it is desired to extract lead from compounds present in the test atmosphere that are insoluble using the dissolution procedures described herein. The flame atomic absorption method is applicable to the determination of masses of approximately 1 g to 200 g of lead per sample, without dilution [1]. The electrothermal atomic absorption method is applicable to the determination of masses of approximately 0,01 g to 0,5 g of lead per sample, without dilution [1]. The ultrasonic extraction procedure has been validated for the determination of masses of approximately 20 g to 100 g of lead per sample, for laboratory-generated lead fume air filter samples [2]. The concentration range for lead in air for which this procedure is applicable is determined in part by the sampling procedure selected by the user (see 10.1).


ISO 16000-27:2014

Indoor air - Part 27: Determination of settled fibrous dust on surfaces by SEM (scanning electron microscopy) (direct method)

ISO 16000-27:2014 specifies a method giving an index for the numerical concentration of fibrous structures with fibres equal or greater than 0,2 µm in diameter in settled dust on surfaces and their classification into specific substance groups (e.g. chrysotile, amphibole asbestos, other inorganic fibres). It is primarily applicable to indoor areas, but it is also suitable for certain outdoor situations. A sampling technique for collection of settled dust using adhesive tape is described. The method incorporates an analytical method for evaluation of the collected samples by scanning electron microscopy. The result can be specified in asbestos structures per unit area and/or classified into four different loading classes. The analytical sensitivity depends on the area examined and can be as low as 10 structures/cm 2 . For the purpose of ISO 16000-27:2014, an asbestos or fibrous structure is defined as an asbestos or (other inorganic/organic) fibre-containing particle regardless of its diameter. The use of the sampling method described is limited, depending on the structure and type of the surface (minor roughness and curvature) and the thickness of dust layer. If the dust layer is too thick, the dust layer can be sampled by other means and eventually analysed as powder sample. It is assumed that the settled dust has particle diameters mostly below 1 mm.


ASTM D7948-20

Standard Test Method for Measurement of Respirable Crystalline Silica in Workplace Air by Infrared Spectrometry

1.1 This standard specifies a test method for collection and analysis of samples of airborne particulate matter for measurement of respirable crystalline silica by infrared (IR) spectrometry. 1.2 This test method is applicable to the analysis of crystalline silica (the polymorphs quartz, cristobalite and tridymite) over a working range of 0.025 to 0.4 mg/m 3 for a 400 L air sample or 0.02 to 0.25 mg/m 3 for a 1000 L air sample, depending on the analytical method. 1.3 The methodology is applicable to personal sampling of the respirable fraction of airborne particles and to static (area) sampling. 1.4 This test method describes three different procedures for sample preparation and infrared analysis of airborne crystalline silica samples, which are delineated in Annex A1 Annex A3 , respectively: ( 1 ) a potassium bromide (KBr) disc IR measurement method, ( 2 ) indirect IR analysis after redeposition onto a filter used for measurement, and ( 3 ) direct on-filter IR analysis. 1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.


ASTM D7035-21

Standard Test Method for Determination of Metals and Metalloids in Airborne Particulate Matter by Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES)

1.1 This test method specifies a procedure for collection, sample preparation, and analysis of airborne particulate matter for the content of metals and metalloids using inductively coupled plasma-atomic emission spectrometry (ICP-AES). The method is generally applicable to occupational exposure monitoring. 1.2 This test method is applicable to personal sampling of the inhalable or respirable fraction of airborne particles and to area sampling. 1.3 This test method should be used by analysts experienced in the use of ICP-AES, the interpretation of spectral and matrix interferences, and procedures for their correction. 1.4 This test method specifies a number of alternative methods for preparing test solutions from samples of airborne particulate matter. One of the specified sample preparation methods is applicable to the measurement of soluble metal or metalloid compounds. Other specified methods are applicable to the measurement of total metals and metalloids. 1.5 It is the user's responsibility to ensure the validity of this test method for sampling materials of untested matrices. 1.6 The following is a non-exclusive list of metals and metalloids for which one or more of the sample dissolution methods specified in this document is applicable. However, there is insufficient information available on the effectiveness of dissolution methods for those elements in italics. 1.7 This test method is not applicable to the sampling of elemental mercury, or to inorganic compounds of metals and metalloids that are present in the gaseous or vapor state. 1.8 No detailed operating instructions are provided because of differences among various makes and models of suitable ICP-AES instruments. Instead, the analyst shall follow the instructions provided by the manufacturer of the particular instrument. This test method does not address comparative accuracy of different devices or the precision between instruments of the same make and model. 1.9 This test method contains notes that are explanatory and are not part of the mandatory requirements of this test method. 1.10 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.11 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.12 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.


ASTM D6785-20

Standard Test Method for Determination of Lead in Workplace Air Using Flame or Graphite Furnace Atomic Absorption Spectrometry

1.1 This standard specifies flame and graphite furnace atomic absorption spectrometric methods for the determination of the time-weighted average mass concentration of particulate lead and lead compounds in workplace air. 1.2 The method is applicable to personal sampling of the inhalable fraction of airborne particles, as defined in ISO 7708, and to static (area) sampling. 1.3 The sample dissolution procedure specifies hot plate or microwave digestion, or ultrasonic extraction ( 10.2 ). The sample dissolution procedure is not effective for all lead compounds (see Section 5 ). The use of an alternative, more vigorous dissolution procedure is necessary when it is desired to extract lead from compounds present in the test atmosphere that are insoluble using the dissolution procedures described herein. For example if it is desired to determine silicate lead, a hydrofluoric acid dissolution procedure is required. 1.4 The flame atomic absorption method is applicable to the determination of masses of approximately 1 to 200 g of lead per sample, without dilution ( 1 ) . 2 The graphite furnace atomic absorption method is applicable to the determination of masses of approximately 0.01 to 0.5 g of lead per sample, without dilution ( 1 ) . 1.5 The ultrasonic extraction procedure has been validated for the determination of masses of approximately 20 to 100 g of lead per sample, for laboratory-generated lead fume air filter samples ( 2 ) . 1.6 The concentration range for lead in air for which this procedure is applicable is determined in part by the sampling procedure selected by the user (see Section 9 ). 1.7 Anions that form precipitates with lead may interfere, but this potential interference is overcome by the addition of the disodium salt of ethylenediamine tetraacetic acid (EDTA) when necessary. 1.8 The values stated in SI units are to be regarded as the standard. No other units of measurement are included in this standard. 1.9 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.10 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.


ASTM D6832-13(2018)

Standard Test Method for the Determination of Hexavalent Chromium in Workplace Air by Ion Chromatography and Spectrophotometric Measurement Using 1,5-diphenylcarbazide

1.1 This test method specifies a method for the determination of the time-weighted average mass concentration of hexavalent chromium in workplace air samples. 1.2 This test method is applicable to the personal sampling of the inhalable fraction of airborne particles, as defined in ISO 7708, and to area (static) sampling. 1.3 The sample dissolution procedure specifies separate procedures for soluble and insoluble hexavalent chromium. 1.4 This test method is applicable to the determination of masses of 0.01 g to 10 g of hexavalent chromium per sample without dilution. 1.5 The concentration range for hexavalent chromium in air for which this procedure is applicable is approximately 0.1 g/m 3 to 100 g/m 3 , assuming 1 m 3 of air sample. The range can be extended upwards by appropriate dilution. 1.6 Interconversion of trivalent and hexavalent chromium species may occur during sampling and sample preparation, but these processes are minimized to the extent possible by the sampling and sample preparation procedures employed. 1.7 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.8 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.9 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.


ASTM D6877-13(2018)

Standard Test Method for Monitoring Diesel Particulate Exhaust in the Workplace

1.1 This test method covers determination of organic and elemental carbon ( OC and EC ) in the particulate fraction of diesel engine exhaust, hereafter referred to as diesel particulate matter ( DPM ). Samples of workplace atmospheres are collected on quartz-fiber filters. The method also is suitable for other types of carbonaceous aerosols and has been widely applied to environmental monitoring. It is not appropriate for sampling volatile or semi-volatile components. These components require sorbents for efficient collection. Note 1: Sample collection and handling procedures for environmental samples differ from occupational samples. This standard addresses occupational monitoring of DPM in workplaces where diesel-powered equipment is used. 1.2 The method is based on a thermal-optical technique ( 1 , 2 ) . 2 Speciation of OC and EC is achieved through temperature and atmosphere control, and an optical feature that corrects for sample charring (carbonization). 1.3 A portion of a 37-mm, quartz-fiber filter sample is analyzed. Results for the portion are used to calculate the total mass of OC and EC on the filter. The portion must be representative of the entire filter deposit. If the deposit is uneven, two or more representative portions should be analyzed for an average. Alternatively, the entire filter can be analyzed, in multiple portions, to determine the total mass. Open-faced cassettes give even deposits but may not be practical. At 2 L/min, closed-face cassettes generally give results equivalent to open-face cassettes if other dusts are absent. Higher flow rates may be employed, but closed-faced cassettes operated at higher flow rates (for example, 5 L/min) sometimes have uneven deposits due to particle impaction at the center of the filter. Other samplers may be required, depending on the sampling environment ( 2- 5 ) . 1.4 The calculated limit of detection ( LOD ) depends on the level of contamination of the media blanks ( 5 ) . A LOD of approximately 0.2- g carbon per cm 2 of filter was estimated when analyzing a sucrose standard solution applied to filter portions cleaned immediately before analysis. LOD s based on media blanks stored after cleaning are usually higher. LOD s based on a set of media blanks analyzed over a six month period at a commercial laboratory were OC = 1.2 g/cm 2 , EC = 0.4 g/cm 2 , and TC = 1.3 g/cm 2 , where TC refers to total carbon ( TC = OC + EC ). In practice, the LOD estimate provided by a laboratory is based on results for a set of media blanks submitted with the samples. To reduce blank variability (due to lack of loading), a manual OC-EC split is assigned at the time when oxygen is introduced. With manual splits, the SD for media blanks is typically about 0.02 0.03 g EC/cm 2 , giving LODs (3 SD blank) from about 0.06 0.09 g EC/cm 2 . The corresponding air concentration depends on the deposit area (filter size) and air volume. 1.5 OC-EC methods are operational, which means the analytical procedure defines the analyte. The test method offers greater selectivity and precision than thermal techniques that do not correct for charring of organic components. The analysis method is simple and relatively quick (about 15 min). The analysis and data reduction are automated, and the instrument is programmable (different methods can be saved as methods for other applications). 1.6 A method (5040) for DPM based on thermal-optical analysis has been published by the National Institute for Occupational Safety and Health (NIOSH). Method updates ( 3 , 4 ) have been published since its initial (1996) publication in the NIOSH Manual of Analytical Methods ( NMAM ). Both OC and EC are determined by NMAM 5040. An EC exposure marker (for DPM ) was recommended because EC is a more selective measure of exposure. A comprehensive review of the method and rationale for selection of an EC marker are provided in a Chapter of NMAM ( 5 ) . 1.7 The thermal-optical instrument required for the analysis is manufactured by a private laboratory. 3 As with most instrumentation, design improvements continue to be made. Different laboratories may be using different instrument models. 1.8 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.9 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in 7.1.5 , 8.3 , and 12.12.2 . 1.10 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.


ASTM D6062-19

Standard Guide for Personal Samplers of Health-Related Aerosol Fractions

1.1 This guide defines conventions for personal samplers of specific particle-size-dependent fractions of any given non-fibrous airborne aerosol. Such samplers are used for assessing health effects and in the setting of and testing for compliance with permissible exposure limits in the workplace and ambient environment. The conventions have been adopted by the International Standards Organization (ISO 7708), the Comit Europ en de Normalisation (CEN EN 481), and the American Conference of Governmental Industrial Hygienists (ACGIH) ( 1 ) . 2 The conventions were developed ( 2 ) in part from health-effects studies reviewed ( 3 ) by the ACGIH and in part as a compromise between definitions proposed by the ACGIH ( 3 ) and by the British Medical Research Council (BMRC) ( 4 ) . Conventions are given here for inhalable, thoracic, and respirable fractions. 1.2 This guide is complementary to Test Method D4532 , which describes the performance of respirable dust cyclones and operational procedures for use. The procedures, specifically the optimal flow rate, are still valid although the estimated accuracy differs somewhat from use with previous aerosol fraction definitions. Details on these instruments have been published ( 5- 11 ) . 1.3 Limitations: 1.3.1 The definitions given here were adopted by the agencies listed in 1.1 in part on the basis of expected health effects of the different size fractions, but in part allowing for available sampling equipment. The original adoption by CEN was, in fact, for the eventual setting of common standards by the EC countries while permitting the use of a variety of instrumentation. Deviations of the sampling conventions from health-related effects are as follows: 1.3.1.1 The inhalable fraction actually depends on the specific air speed and direction, on the breathing rate, and on whether breathing is by nose or mouth. The values given in the inhalable convention are for representative values of breathing rate and represent averages over all wind directions. 1.3.1.2 The respirable and thoracic fractions vary from individual to individual and with the breathing pattern. The conventions are approximations to the average case. 1.3.1.3 Each convention applies strictly to a fraction penetrating to a region, rather than depositing. Therefore, samples collected according to the conventions may only approximate correlations with biological effects. For example, the respirable convention overestimates the fraction of very small particles deposited in the alveolar region of the respiratory system because some of the particles are actually exhaled without being deposited ( 12 ) . In many workplaces, these very small particles contribute insignificantly to the sampled mass. Furthermore, the large variability between individuals and the details of clearance may be as important as this type of effect. 1.3.1.4 The thoracic convention applies to mouth breathing, for which aerosol collection is greater than during nose breathing. 1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.


ASTM D6056-96(2011)

Standard Test Method for Determining Concentration of Airborne Single-Crystal Ceramic Whiskers in the Workplace Environment by Transmission Electron Microscopy

1.1 This test method covers the sampling methods and analysis techniques used to assess the airborne concentration and size distribution of single-crystal ceramic whiskers (SCCW), such as silicon carbide and silicon nitride, which may occur in and around the workplace where these materials are manufactured, processed, transported, or used. This test method is based on the filtration of a known quantity of air through a filter. The filter is subsequently evaluated with a transmission electron microscope (TEM) for the number of fibers meeting appropriately selected morphological and compositional criteria. This test method has the ability to distinguish among different types of fibers based on energy dispersive X-ray spectroscopy (EDS) analysis and selected area electron diffraction (SAED) analysis. This test method may be appropriate for other man-made mineral fibers (MMMF). 1.2 This test method is applicable to the quantitation of fibers on a collection filter that are greater than 0.5 m in length, less than 3 m in width, and have an aspect ratio equal to or greater than 5:1 (1) . The data are directly convertible to a statement of concentration per unit volume of air sampled. This test method is limited by the amount of coincident interference particles. 1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only. 1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.


ASTM D6057-96(2011)

Standard Test Method for Determining Concentration of Airborne Single-Crystal Ceramic Whiskers in the Workplace Environment by Phase Contrast Microscopy

1.1 This test method covers the sampling methods and analysis techniques used to assess the airborne concentration of single-crystal ceramic whiskers (SCCW), such as silicon carbide and silicon nitride, which may occur in and around the workplace where these materials are manufactured, processed, transported, or used. This test method is based on the collection of fibers by filtration of a known quantity of air through a filter. The filter is subsequently evaluated with a phase contrast microscope (PCM) for the number of fibers meeting appropriately selected counting criteria. This test method cannot distinguish among different types of fibers. This test method may be appropriate for other man-made mineral fibers (MMMF). 1.2 This test method is applicable to the quantitation of fibers on a collection filter that are greater than 5 m in length, less than 3 m in width, and have an aspect ratio equal to or greater than 5:1. The data are directly convertible to a statement of concentration per unit volume of air sampled. This test method is limited by the diameter of the fibers visible by PCM (typically greater than 0.25 m in width) and the amount and type of coincident interference particles. 1.3 A more definitive analysis may be necessary to confirm the identity and dimensions of the fibers located with the PCM, especially where other fiber types may be present. Such techniques may include scanning electron microscopy (SEM) or transmission electron microscopy (TEM). The use of these test methods for the identification and size determination of SCCW is described in Practice D6058 and Test Methods D6059 and D6056 . 1.4 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only. 1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.


ASTM D6059-96(2011)

Standard Test Method for Determining Concentration of Airborne Single-Crystal Ceramic Whiskers in the Workplace Environment by Scanning Electron Microscopy

1.1 This test method covers the sampling methods and analysis techniques used to assess the airborne concentration and size distribution of single-crystal ceramic whiskers (SCCW), such as silicon carbide and silicon nitride, which may occur in and around the workplace where these materials are manufactured, processed, transported, or used. This test method is based on the collection of fibers by filtration of a known quantity of air through a filter. The filter is subsequently evaluated with a scanning electron microscope (SEM) for the number of fibers meeting appropriately selected morphological and compositional criteria. This test method has the ability to distinguish among many different types of fibers based on energy dispersive X-ray spectroscopy (EDS) analysis. This test method may be appropriate for other man-made mineral fibers (MMMF). 1.2 This test method is applicable to the quantitation of fibers on a collection filter that are greater than 5 m in length, less than 3 m in width, and have an aspect ratio equal to or greater than 5:1. The data are directly convertible to a statement of concentration per unit volume of air sampled. This test method is limited by the diameter of the fibers visible by SEM (typically greater than 0.10 to 0.25 m in width as determined in 12.1.5) and the amount of coincident interference particles. 1.3 A more definitive analysis may be necessary to confirm the presence of fibers with diameters 0.10 to 0.25 m in width. For this purpose, a transmission electron microscope (TEM) is appropriate. The use of the TEM method for the identification and size measurement of SCCW is described in Practice D6058 and Test Method D6056 . 1.4 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only. 1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.


BS EN 13205-2:2014

Workplace exposure. Assessment of sampler performance for measurement of airborne particle concentrations. Laboratory performance test based on determination of sampling efficiency (British Standard)

This part of EN 13205 specifies a laboratory performance test for samplers for the inhalable, thoracic and respirable aerosol fractions, based on determining the sampling efficiency curve of a candidate sampler at a minimum of nine particle sizes. It specifies methods for testing aerosol samplers under prescribed laboratory conditions in order to test whether the performance of a candidate sampler fulfils therequirements of EN 13205-1.


BS EN 13205-4:2014

Workplace exposure. Assessment of sampler performance for measurement of airborne particle concentrations. Laboratory performance test based on comparison of concentrations (British Standard)

EN 13205-4 describes procedures for determining the performance of a candidate sampler in a comparative test with a validated sampler, in a laboratory test. These comparison tests are suited to samplers that physically separate particles from their carrier gas by aerodynamic processes, or additionally to any other aerosol sampler intended for measuring the concentration of aerosol particles in a gas.


BS EN 13936:2014

Workplace exposure. Procedures for measuring a chemical agent present as a mixture of airborne particles and vapour. Requirements and test methods (British Standard)

This European Standard specifies performance requirements and test methods for the evaluation of procedures for measuring a chemical agent present as a mixture of airborne particles and vapour in workplace air. This European Standard establishes general principles to enable developers and users of mixed-phase samplers and methods to adopt a consistent approach to method validation and provides a framework for the assessment of method performance in accordance with EN 482. Annex A of this European Standard gives guidance on possible approaches to sample mixtures of airborne particles and vapour and Annex B gives information about their physical behaviour. This European Standard is not applicable to methods that differentiate between the sampled airborne particles and vapour. This European Standard is not applicable to a chemical agent present in different chemical and physical forms (for example, mercury in the form of Hg (0) and Hg (II)).


BS EN ISO 21832:2020

Workplace air. Metals and metalloids in airborne particles. Requirements for evaluation of measuring procedures (British Standard)

This document specifies performance requirements and test methods for the evaluation of procedures for measuring metals and metalloids in airborne particles sampled onto a suitable collection substrate. This document specifies a method for estimating the uncertainties associated with random and systematic errors and combining them to calculate the expanded uncertainty of the measuring procedure as a whole, as prescribed in ISO 20581. This document is applicable to measuring procedures in which sampling and analysis is carried out in separate stages, but it does not specify performance requirements for collection, transport and storage of samples, since these are addressed in EN 13205-1 and ISO 15767. This document does not apply to procedures for measuring metals or metalloids present as inorganic gases or vapours (e.g. mercury, arsenic) or to procedures for measuring metals and metalloids in compounds that could be present as a particle/vapour mixture (e.g. arsenic trioxide).



BS EN 481:1993

Workplace atmospheres. Size fraction definitions for measurement of airborne particles (British Standard)

This standard defines sampling conventions for particle size fractions which are to be used in assessing the possible health effects resulting from inhalation of airborne particles in the workplace. They are derived from experimental data for healthy adults. Conventions are defined for the inhalable, thoracic and respirable fractions; extrathoracic and tracheobronchial conventions may be calculated from the defined conventions.


BS EN ISO 13982-1:2004+A1:2010

Protective clothing for use against solid particulates. Performance requirements for chemical protective clothing providing protection to the full body against airborne solid particulates (type 5 clothing) (British Standard)

ISO 13982-1:2004 specifies the minimum requirements for chemical protective clothing resistant to penetration by airborne solid particles (Type 5). These garments are full-body protective clothing, i.e. covering trunk, arms and legs, such as one-piece coveralls or two piece suits, with or without hood or visors, with or without foot protection. Requirements for component parts, such as hoods, gloves, boots, visors or respiratory protective equipment might be specified in other International and European Standards. ISO 13982-1:2004 is applicable only to airborne solid particulates. It is not applicable to other forms of challenge by solid chemicals, e.g. penetration of chemical dust through materials by rubbing or flexing, which may form the object of separate standards.


BS EN 1093-8:1998+A1:2008

Safety of machinery. Evaluation of the emission of airborne hazardous substances. Pollutant concentration parameter, test bench method (British Standard)

This European Standard specifies a test bench method for the measurement of the pollutant concentration parameter of a specified airborne hazardous substance from machines using a test bench under specified operating conditions. This method is only applicable for the determination of emitted gases, vapours and respirable particles. The determination of the emission rate in a test bench (see EN 1093-3) shall be used when possible. Measurement of the pollutant concentration parameter of a machine can serve for the: a) evaluation of the performance of a machine; b) evaluation of the improvement of the machine; c) comparison of machines within groups of machines with the same intended use (groups are defined by the function and materials processed), d) ranking of machines from the same group according to their pollutant concentration parameters; e) determination of the state of the art of machines with respect to their pollutant concentration parameter.


BS ISO 15202-1:2020

Workplace air. Determination of metals and metalloids in airborne particulate matter by inductively coupled plasma atomic emission spectrometry Sampling (British Standard)

ISO 15202-1:2012 specifies a method for collecting samples of airborne particulate matter for subsequent determination of metals and metalloids using inductively coupled plasma ? atomic emission spectrometry (ICP-AES). Samples obtained using the method described herein can also be subsequently analysed for elemental composition by other instrumental methods, such as atomic absorption spectrometry (AAS) or inductively coupled plasma mass spectrometry (ICP-MS). The method is not applicable to the sampling of mercury, which is present in air in the vapour phase at ambient temperatures; inorganic compounds of metals and metalloids that are permanent gases, e.g. arsine (AsH 3 ); or inorganic compounds of metals and metalloids that are present in the vapour phase at ambient temperatures, e.g. arsenic trioxide (As 2 O 3 ). The method is applicable to personal sampling of the inhalable or respirable fraction of airborne particles, as defined in ISO 7708, and to static sampling.


BS ISO 16740:2005

Workplace air. Determination of hexavalent chromium in airborne particulate matter. Method by ion chromatography and spectrophotometric measurement using diphenyl carbazide (British Standard)

ISO 16740:2005 specifies a method for the determination of the time-weighted average mass concentration of hexavalent chromium in workplace air. Separate sample preparation methods are specified for the extraction of soluble and insoluble hexavalent chromium. The method for insoluble hexavalent chromium can also be used to prepare samples for determination of total hexavalent chromium, if desired. ISO 16740:2005 is applicable to the personal sampling of the inhalable fraction of airborne particles, as defined in ISO 7708, and to static (area) sampling. The analytical method is applicable to the determination of masses of 0,01 micrograms to 10 micrograms of hexavalent chromium per sample, without dilution. The concentration range of hexavalent chromium in air for which the measuring procedure is applicable is determined by the sampling method selected by the user. For a 1 cubic metre air sample, without sample dilution, the working range is approximately 0,01 micrograms per cubic metre to 10 micrograms per cubic metre.


BS ISO 21501-4:2018

Determination of particle size distribution. Single particle light interaction methods. Light scattering airborne particle counter for clean spaces (British Standard)

This document describes a calibration and verification method for a light scattering airborne particle counter (LSAPC), which is used to measure the size distribution and particle number concentration of particles suspended in air. The light scattering method described in this document is based on single particle measurements. The typical size range of particles measured by this method is between 0,1 m and 10 m in particle size. Instruments that conform to this document are used for the classification of air cleanliness in cleanrooms and associated controlled environments in accordance with ISO 14644 1 and ISO 14644 2, as well as the measurement of number and size distribution of particles in various environments. The following parameters are within the scope of this document: size setting error; counting efficiency; size resolution; false count; maximum particle number concentration; sampling flow rate error; sampling time error; response rate; calibration interval; reporting results from test and calibration.


PD CEN/TR 15230:2005

Workplace atmospheres. Guidance for sampling of inhalable, thoracic and respirable aerosol fractions (British Standard)

This Technical Report describes methods that are suitable for the determination of the health-related fractions of most aerosols in the workplace. For more complex aerosols such as bioaerosols, fibres, radioactive aerosols and particle-vapour mixtures further considerations are necessary (see e.g. relevant standards). This Technical Report is not applicable to the monitoring of airborne particle concentrations using direct-reading instruments.


CSA N288.2-2019

Guidelines for calculating the radiological consequences to the public of a release of airborne radioactive material for nuclear reactor accidents

Preface This is the third edition of CSA N288.2, Guidelines for calculating the radiological consequences to the public of a release of airborne radioactive material for nuclear reactor accidents. It supersedes the previous editions published in 2014 and 1991 under the title Guidelines for calculating radiation doses to the public from a release of airborne radioactive material under hypothetical accident conditions in nuclear reactors. This Standard is part of a series of Standards on environmental management for nuclear facilities. This Standard describes acceptable methods for modelling the consequences of accidents at nuclear reactors for safety assessment and real-time emergency response. This Standard also identifies acceptable data sources and acceptable methodologies to account for specific effects, and recommends standardized end points for the calculations. This edition has been updated to reflect current industry practice and new research and analysis methods. Major changes to this edition include the following: a) The definitions have been updated for consistency with the CSA N288 series of Standards. b) Administrative provisions (e.g., the term "Class 1") were removed. c) Additional clarification in areas identified by users was added. d) The definitions for "beyond design basis accidents (BDBA)" and "severe accident" were aligned with the definitions provided in CSA N290.16-16. Users of this Standard are reminded that the site selection, design, manufacture, construction, installation, commissioning, operation, and decommissioning of nuclear facilities in Canada are subject to the Nuclear Safety and Control Act and its Regulations. The Canadian Nuclear Safety Commission might impose additional requirements to those specified in this Standard. The CSA N-Series Standards provide an interlinked set of requirements for the management of nuclear facilities and activities. CSA N286 provides overall direction to management to develop and implement sound management practices and controls, while the other CSA Group nuclear Standards provide technical requirements and guidance that support the management system. This Standard works in harmony with CSA N286 and does not duplicate the generic requirements of CSA N286; however, it may provide more specific direction for those requirements. Scope 1.1 Type of consequence assessments This Standard proposes methods for modelling the consequences of accidents at nuclear reactors for safety assessment and real-time emergency response. Notes: 1) Models used to assess the consequences of a postulated accident for safety assessment purposes have much in common with those used for a real-time nuclear accident for emergency response purposes, including the calculation of dispersion and air concentrations. However, the two types of models differ in their treatment of source terms and end points. 2) Safety assessment is a prospective activity that includes a) deterministic and probabilistic calculations carried out for Authority Having Jurisdiction (AHJ) requirements; b) probabilistic risk assessment for cost-benefit analyses; and c) deterministic and probabilistic calculations carried out for emergency planning purposes. 3) Emergency response consequence assessment is carried out during a real emergency in support of the protection of the public and the environment. Emergency planning consequence assessment is performed for postulated accidents in support of preparedness activities such as locating reception centres for evacuees and training emergency responders. 4) All nuclear accident plant states are included within the scope of this Standard. (Refer to REGDOC 2.5.2.) 1.2 Facilities This Standard is designed to provide guidance on how to model the consequences of accidental radiological releases to the atmosphere from nuclear reactor facilities. When using this Standard with facilities other than nuclear reactors, the user is instructed to exercise caution. In these cases, the user of the Standard is responsible for determining its applicability. Note: The range of distances discussed in Clause 1.5 might not be appropriate for small nuclear reactors and thus, it is the user’s responsibility to identify models that would be applicable at less than 300 m. 1.3 Operating conditions This Standard is applicable when nuclear material is released to the atmospheric environment as a result of an accident at a nuclear reactor, subject to the exclusions of Clause 1.10. Parts of this Standard may be applicable to the consequence assessment of the airborne emissions from anticipated operational occurrences (AOO). In these cases, the user is responsible for determining the applicability of this Standard. 1.4 Time scale This Standard applies to short-term accidental releases from a nuclear reactor with a duration of a month or less. Note: Methods of estimating doses for release durations beyond 30 days are beyond the scope of this Standard, but are addressed by other guidance such as that provided in CSA N288.1. 1.5 Spatial scale This Standard covers local atmospheric dispersion, which for Gaussian plume models is defined as dispersion that occurs in the range of 300 m to 100 km. Notes: 1) The lower limit was set at 300 m since specialized models are required for closer distances and members of the public rarely reside closer than this. Further downwind, the predictions of the local dispersion models discussed in this Standard are fairly reliable to distances of 20 km. Uncertainties become larger as the distance increases and the local dispersion models become unreliable for individual dose calculations beyond 50 km (see Clause 7.2.6). For individual dose calculations beyond 50 km, see Clause 4.6.4. 2) Emergency response applications can require the range of validity to extend to 50 km despite the reduced accuracy. The accuracy of the Gaussian model limits its application for calculation of individual dose to distances less than 50 km. Nevertheless, the use of Gaussian models is acceptable when calculating the collective dose, because for such aggregate quantities, the errors tend to cancel. The model’s applicability to 100 km covers the need to calculate collective doses incorporating the major urban areas in the vicinity. Doses beyond 100 km make a relatively small contribution to collective doses (see Clause 7.14.2). 3) The user is responsible for interpreting the individual dose in the case of airborne releases from a site with multiple reactor units. 4) At distances greater than this scale, advanced models might be used with appreciation for the limitations of the model being considered. 1.6 Meteorological sampling This Standard covers both a) single weather scenario approaches (deterministic calculations); and b) probabilistic sampling of meteorological data records. 1.7 Pathways Models for the dispersion (transport and diffusion) and fate of radioactive contaminants released to the atmosphere are covered in this Standard. This Standard includes pathways for immersion in the airborne plume (cloudshine), external exposure to contaminated ground (groundshine), and inhalation. Absorption of tritiated water (HTO) vapour through the skin is included in the inhalation pathway. Note: The ingestion pathway might not be relevant to the time scale covered in this Standard. 1.8 Contaminants This Standard covers airborne radioactive contaminants that could be released accidentally from nuclear reactors in the form of gases, particles, and water vapour. 1.9 Receptors and end points This Standard applies to receptors (see Clause 7.2) and end points (see Clause 7.4) that can be affected by radiological contaminants released from a nuclear facility. The calculation of the following quantities is part of this Standard: a) air and ground concentration of contaminants; and b) the doses and health effects in representative persons (including workers located more than 300 m from the release and members of the public). 1.10 Exclusions 1.10.1 Routine releases during normal operation This Standard does not address emissions that occur as a result of normal operation of a nuclear facility, which are addressed in a separate Standard (CSA N288.1). The models and assumptions are different when a release is spread over many years, when it is of small magnitude, and when humans remain in the vicinity of the source, carrying out their normal activities. 1.10.2 Spills and liquid releases This Standard does not address spills and accidental release of radioactive contaminants to surface or ground water. However, air emissions arising from such a spill are considered, as depletion of airborne radioactivity by deposition to water is included in the Standard if there is a water body between the source and the receptor, but surface water transport is not included. 1.10.3 Urban dispersion Most urban dispersion effects (street canyon, differential heating of street walls, etc.) are beyond the scope of this Standard. Enhanced dilution due to the large surface roughness length of urban areas may be taken into account in calculating the vertical dispersion parameter (e.g., see Clause B.1.12). 1.10.4 Fire and explosions This Standard does not apply to the release of radioactive material coincident with and caused by fire or explosion. This Standard does not deal with special applications such as malevolent acts. 1.10.5 Hurricanes and tornados Severe weather conditions such as hurricanes and tornadoes are not addressed in this Standard. The rationale for excluding these scenarios is that they are associated with high winds and complex wind fields that result in enhanced dispersion and lower concentrations relative to more normal weather conditions. 1.10.6 Regional and global dispersion Regional (or mesoscale) and global dispersion are excluded since consequences are expected to be very low beyond 100 km. This Standard focuses on local dispersion (distances less than 100 km). 1.10.7 Chemical contaminants This Standard does not apply to non-radioactive contaminants or toxicity due to radionuclides. This Standard does therefore not address extreme concentrations as end points or atmospheric chemistry. Note: Examples of non-radioactive contaminants include toxic, corrosive, or environmentally deleterious substances. 1.10.8 Ingestion pathway The ingestion pathway is not covered by this Standard. 1.10.9 Economic costs including those arising from off-site interventions This Standard does not address those economic consequences, such as those arising from evacuation, food replacement, and eventual remediation, associated with a nuclear accident from a nuclear reactor facility. The simulation of protective actions such as evacuation and sheltering of the population during an emergency is not covered in this Standard, but the dose reduction factor associated with indoor occupancy after an accident can be included. 1.10.10 Logistics of protective actions Although this Standard covers the calculation of doses for emergency planning purposes, it does not include the assessment of the logistics of protective actions for the public. 1.10.11 Non-human biota Doses and effects on non-human biota are not covered by this Standard. Note: See CSA N288.6 for dose and effects on non-human biota during normal operations. 1.11 Terminology In this Standard, "shall" is used to express a requirement, i.e., a provision that the user is obliged to satisfy in order to comply with the standard; "should" is used to express a recommendation or that which is advised but not required; and "may" is used to express an option or that which is permissible within the limits of the Standard. Notes accompanying clauses do not include requirements or alternative requirements; the purpose of a note accompanying a clause is to separate from the text explanatory or informative material. Notes to tables and figures are considered part of the table or figure and may be written as requirements. Annexes are designated normative (mandatory) or informative (non-mandatory) to define their application.


AS 2365.7-2006

Methods for sampling and analysis of indoor air - Determination of total suspended particulate matter - Gravimetric method (FOREIGN STANDARD)

Sets out requirements for a method for the sample collection and gravimetric analysis of suspended particles in indoor air. Suspended particles are emitted from indoor air from a number of sources, including cigarette smoke, food cooking and space heating.


ASTM D6271-10(2016)

Standard Test Method for Estimating Contribution of Environmental Tobacco Smoke to Respirable Suspended Particles Based on Solanesol

1.1 This test method covers the sampling/analysis of respirable suspended particles (RSP) and the estimation of the RSP fraction attributable to environmental tobacco smoke (ETS). The test method is based on collection of total RSP on a membrane filter, extraction of the filter in methanol, and determination of solanesol, a C 45 isoprenoid alcohol, by high performance liquid chromatography (HPLC) with ultraviolet (UV) detection. 1.2 This test method is compatible with the determinations of gravimetric RSP, ultraviolet particulate matter (UVPM), and fluorescent particulate matter (FPM) (see Test Methods D5955 ), but does not require them. UVPM and FPM, which are based on the ultraviolet absorbance and fluorescence of the filter extract, are also used to estimate the contribution of ETS to RSP. 1.3 The sampling components consist of a 1.0- m pore size polytetrafluoroethylene (PTFE) membrane filter in a filter cassette connected on the inlet end to a particle size separating device and, on the outlet end, to a sampling pump. This test method is applicable to personal and area sampling. 1.4 This test method is limited in sample duration only by the capacity of the membrane filter. The test method has been evaluated up to 24-h sample duration; a minimum sample duration of 1 h is recommended. 1.5 Limits of detection (LOD) for this test method at a sampling rate of 2 L/min are 0.042 g/m 3 for 1-h sample duration and 0.005 g/m 3 for 8-h sample duration. 1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.7 This standard does not purport to address all the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific precautionary information is given in 13.6 .


ASTM D5955-02(2017)e1

Standard Test Methods for Estimating Contribution of Environmental Tobacco Smoke to Respirable Suspended Particles Based on UVPM and FPM

1.1 These test methods pertain to the sampling/analysis of respirable suspended particles (RSP) and the estimation of the RSP fraction attributable to environmental tobacco smoke (ETS). These test methods are based on collection of total RSP on a membrane filter, extracting the collected material in methanol, and measuring total ultraviolet absorbance or fluorescence, or both, of this extract. The corresponding methods of estimation are termed ultraviolet particulate matter (UVPM) and fluorescent particulate matter (FPM), respectively. 1.2 These test methods are compatible with, but do not require the determination of solanesol, which is also used to estimate the contribution of ETS to RSP (see Test Method D6271 ). 1.3 The sampling components consist of a preweighed, 1.0- m pore size polytetrafluoroethylene (PTFE) membrane filter in a filter cassette connected on the inlet end to a particle size separating device and, on the outlet end, to a sampling pump. These test methods are applicable to personal and area sampling. 1.4 These test methods are limited in sample duration only by the capacity of the membrane filter (about 2000 g). These test methods have been evaluated up to a 24-h sample duration with a minimum sample duration of at least 1 h. 1.5 Limits of detection (LOD) and quantitation (LOQ) for the UVPM test method at a sampling rate of 2 L/min are, respectively, 2.5 g/m 3 and 8.3 g/m 3 for a 1-h sample duration and 0.3 g/m 3 and 1.0 g/m 3 for an 8-h sample duration. The LOD and LOQ for the FPM test method at a sampling rate of 2 L/min are, respectively, 1.4 g/m 3 and 4.7 g/m 3 for a 1-h sample duration and 0.2 g/m 3 and 0.6 g/m 3 for an 8-h sample duration. 1.6 Units The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific precautionary information is given in 13.6 . 1.8 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.


ISO 15593:2001

Environmental tobacco smoke -- Estimation of its contribution to respirable suspended particles -- Determination of particulate matter by ultraviolet absorbance and by fluorescence

This International Standard specifies methods for the sampling and determination of respirable suspended particles (RSP) for the estimation of the RSP fraction attributable to environmental tobacco smoke (ETS).


ISO 18144:2003

Environmental tobacco smoke - Estimation of its contribution to respirable suspended particles - Method based on solanesol

ISO 18144:2003 specifies a method for the sampling and determination of respirable suspended particles (RSP) and for the estimation of the RSP fraction attributable to environmental tobacco smoke (ETS). This method is applicable to personal and area sampling. This method is compatible with the determinations of gravimetric RSP, ultraviolet particulate matter (UVPM) and fluorescent particulate matter (FPM), which are also used to estimate the contribution of ETS to RSP.


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